REGULARITIES OF CHANGES IN THE ANTI-CORROSION ACTIVITY OF LOW- AND HIGH-ALKALI SULFONATE ADDITIVES DURING ULTRASONIC TREATMENT IN BASIC OILS OF VARIOUS ORIGIN
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Abstract
The results of the study of the effect of ultrasonic treatment of calcium sulfonate additives on their anticorrosive activity against the surface of low-carbon steel are presented. Ultrasonic treatment of sulfonate additives has been found to be an effective way to increase their anticorrosive activity in base oil solutions. Regularity of change of anticorrosive activity and work of adhesion in relation to surface of low-carbon steel from value of specific energy transferred to sample of sulfonate additive by ultrasonic waves is revealed. The optimal specific energy of ultrasonic waves was determined, at which the anticorrosive activity of sulfonate additives is maximum. Relationship of anticorrosive activity of solutions of sulphonate additives with value of their work of adhesion to surface of steel plate and sizes of forming micelles is revealed. The mechanism of anticorrosive action of sulfonate additives has been clarified. It has been shown, that due to the inhomogeneity of the formed protective film on the surface of steel, the anti-corrosion properties of a high-alkaline sulfonate additive containing a significant amount of calcium carbonate, both before and after sonication, are worse than that of a low-alkaline sulfonate additive.
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